One interesting behavior is that if you completely discharge a capacitor, its voltage will increase again over time as if it was charged.
In the Wikipedia article, a measurement procedure following the IEC/EN 60384-1 standard is described:
- charge the capacitor to its nominal voltage for 1h
- discharge it across 5Ω for 10 seconds
- wait for 15 minutes
- measure its voltage
I've conducted that experiment with a random 16V 1000µF aluminium electrolytic capacitor and got 0.6706V, which is 4.19%.
The image shows the re-charging curve over nearly 2 weeks (note the logarithmic time scale). The voltage reached 1.083V (6.30%).
Just think of a capacitor in a microwave with 4kV. 6.3% would be 252V.
That is dangerous!
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